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Integral Forms for Quantum-Mechanical Momentum Operators

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Zeitschriftentitel: Journal of Mathematical Physics
Personen und Körperschaften: Robinson, Peter D.
In: Journal of Mathematical Physics, 7, 1966, 11, S. 2060-2065
Medientyp: E-Article
Sprache: Englisch
veröffentlicht:
AIP Publishing
Schlagwörter:
author_facet Robinson, Peter D.
Robinson, Peter D.
author Robinson, Peter D.
spellingShingle Robinson, Peter D.
Journal of Mathematical Physics
Integral Forms for Quantum-Mechanical Momentum Operators
Mathematical Physics
Statistical and Nonlinear Physics
author_sort robinson, peter d.
spelling Robinson, Peter D. 0022-2488 1089-7658 AIP Publishing Mathematical Physics Statistical and Nonlinear Physics http://dx.doi.org/10.1063/1.1704889 <jats:p>The usual differential form P0 for the quantum-mechanical momentum operator P which is conjugate to a generalized coordinate q (α ≤ q ≤ β) is, in atomic units, P0 = − i(g−½) ∂/∂q (g½), where g is the Jacobian of the transformation from Cartesian to generalized coordinates. However, P0 is not always self-adjoint on the domain 𝒟 of physically acceptable bound-state wavefunctions, as a proper quantum-mechanical operator should be. An integral form is proposed for P, defined by Pf(q)=(2π)−12g−12(q) ∫ −∞∞exp (ikq)kF(k) dk, α≤q≤β,where F(k)=(2π)−12 ∫ αβexp (−ikξ)f(ξ)g12(ξ) dξ, f∈D. The effect of this integral operator (which is suggested by the ideas of Fourier transforms) differs from that of P0 only at the end-points of the range of q. In a sense, it is formally equivalent to an operator (suggested by Robinson and Hirschfelder) which is obtained by adding certain delta-function terms to P0, but it suffers from none of the defects, since delta-functions do not appear explicitly. Various properties of the integral operator are derived. Some discussion of the domain 𝒟 is presented as an appendix.</jats:p> Integral Forms for Quantum-Mechanical Momentum Operators Journal of Mathematical Physics
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match_str robinson1966integralformsforquantummechanicalmomentumoperators
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recordtype ai
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series Journal of Mathematical Physics
source_id 49
title Integral Forms for Quantum-Mechanical Momentum Operators
title_unstemmed Integral Forms for Quantum-Mechanical Momentum Operators
title_full Integral Forms for Quantum-Mechanical Momentum Operators
title_fullStr Integral Forms for Quantum-Mechanical Momentum Operators
title_full_unstemmed Integral Forms for Quantum-Mechanical Momentum Operators
title_short Integral Forms for Quantum-Mechanical Momentum Operators
title_sort integral forms for quantum-mechanical momentum operators
topic Mathematical Physics
Statistical and Nonlinear Physics
url http://dx.doi.org/10.1063/1.1704889
publishDate 1966
physical 2060-2065
description <jats:p>The usual differential form P0 for the quantum-mechanical momentum operator P which is conjugate to a generalized coordinate q (α ≤ q ≤ β) is, in atomic units, P0 = − i(g−½) ∂/∂q (g½), where g is the Jacobian of the transformation from Cartesian to generalized coordinates. However, P0 is not always self-adjoint on the domain 𝒟 of physically acceptable bound-state wavefunctions, as a proper quantum-mechanical operator should be. An integral form is proposed for P, defined by Pf(q)=(2π)−12g−12(q)  ∫ −∞∞exp (ikq)kF(k) dk,  α≤q≤β,where F(k)=(2π)−12  ∫ αβexp (−ikξ)f(ξ)g12(ξ) dξ,  f∈D. The effect of this integral operator (which is suggested by the ideas of Fourier transforms) differs from that of P0 only at the end-points of the range of q. In a sense, it is formally equivalent to an operator (suggested by Robinson and Hirschfelder) which is obtained by adding certain delta-function terms to P0, but it suffers from none of the defects, since delta-functions do not appear explicitly. Various properties of the integral operator are derived. Some discussion of the domain 𝒟 is presented as an appendix.</jats:p>
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author Robinson, Peter D.
author_facet Robinson, Peter D., Robinson, Peter D.
author_sort robinson, peter d.
container_issue 11
container_start_page 2060
container_title Journal of Mathematical Physics
container_volume 7
description <jats:p>The usual differential form P0 for the quantum-mechanical momentum operator P which is conjugate to a generalized coordinate q (α ≤ q ≤ β) is, in atomic units, P0 = − i(g−½) ∂/∂q (g½), where g is the Jacobian of the transformation from Cartesian to generalized coordinates. However, P0 is not always self-adjoint on the domain 𝒟 of physically acceptable bound-state wavefunctions, as a proper quantum-mechanical operator should be. An integral form is proposed for P, defined by Pf(q)=(2π)−12g−12(q)  ∫ −∞∞exp (ikq)kF(k) dk,  α≤q≤β,where F(k)=(2π)−12  ∫ αβexp (−ikξ)f(ξ)g12(ξ) dξ,  f∈D. The effect of this integral operator (which is suggested by the ideas of Fourier transforms) differs from that of P0 only at the end-points of the range of q. In a sense, it is formally equivalent to an operator (suggested by Robinson and Hirschfelder) which is obtained by adding certain delta-function terms to P0, but it suffers from none of the defects, since delta-functions do not appear explicitly. Various properties of the integral operator are derived. Some discussion of the domain 𝒟 is presented as an appendix.</jats:p>
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imprint AIP Publishing, 1966
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series Journal of Mathematical Physics
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spelling Robinson, Peter D. 0022-2488 1089-7658 AIP Publishing Mathematical Physics Statistical and Nonlinear Physics http://dx.doi.org/10.1063/1.1704889 <jats:p>The usual differential form P0 for the quantum-mechanical momentum operator P which is conjugate to a generalized coordinate q (α ≤ q ≤ β) is, in atomic units, P0 = − i(g−½) ∂/∂q (g½), where g is the Jacobian of the transformation from Cartesian to generalized coordinates. However, P0 is not always self-adjoint on the domain 𝒟 of physically acceptable bound-state wavefunctions, as a proper quantum-mechanical operator should be. An integral form is proposed for P, defined by Pf(q)=(2π)−12g−12(q) ∫ −∞∞exp (ikq)kF(k) dk, α≤q≤β,where F(k)=(2π)−12 ∫ αβexp (−ikξ)f(ξ)g12(ξ) dξ, f∈D. The effect of this integral operator (which is suggested by the ideas of Fourier transforms) differs from that of P0 only at the end-points of the range of q. In a sense, it is formally equivalent to an operator (suggested by Robinson and Hirschfelder) which is obtained by adding certain delta-function terms to P0, but it suffers from none of the defects, since delta-functions do not appear explicitly. Various properties of the integral operator are derived. Some discussion of the domain 𝒟 is presented as an appendix.</jats:p> Integral Forms for Quantum-Mechanical Momentum Operators Journal of Mathematical Physics
spellingShingle Robinson, Peter D., Journal of Mathematical Physics, Integral Forms for Quantum-Mechanical Momentum Operators, Mathematical Physics, Statistical and Nonlinear Physics
title Integral Forms for Quantum-Mechanical Momentum Operators
title_full Integral Forms for Quantum-Mechanical Momentum Operators
title_fullStr Integral Forms for Quantum-Mechanical Momentum Operators
title_full_unstemmed Integral Forms for Quantum-Mechanical Momentum Operators
title_short Integral Forms for Quantum-Mechanical Momentum Operators
title_sort integral forms for quantum-mechanical momentum operators
title_unstemmed Integral Forms for Quantum-Mechanical Momentum Operators
topic Mathematical Physics, Statistical and Nonlinear Physics
url http://dx.doi.org/10.1063/1.1704889