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Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons
Gespeichert in:
Zeitschriftentitel: | Chemistry – A European Journal |
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Personen und Körperschaften: | , |
In: | Chemistry – A European Journal, 25, 2019, 48, S. 11193-11213 |
Medientyp: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
Zusammenfassung: | <jats:title>Abstract</jats:title><jats:p>Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl group, and as a result, molecules bearing multiple sulfones are versatile building blocks. This Review highlights the unique ability of 1,1‐ and 1,2‐bis(sulfones) to masquerade as a vast array of reactive synthons including methane polyanions, vinyl cations, and all‐carbon dipoles that would be difficult or impossible to access directly.</jats:p> |
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Umfang: | 11193-11213 |
ISSN: |
0947-6539
1521-3765 |
DOI: | 10.1002/chem.201902019 |