Eintrag weiter verarbeiten
Buchumschlag von Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons
Verfügbar über Online-Ressource

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

Gespeichert in:

Bibliographische Detailangaben
Zeitschriftentitel: Chemistry – A European Journal
Personen und Körperschaften: Trost, Barry M., Kalnmals, Christopher A.
In: Chemistry – A European Journal, 25, 2019, 48, S. 11193-11213
Medientyp: E-Article
Sprache: Englisch
veröffentlicht:
Wiley
Schlagwörter:
Details
Zusammenfassung: <jats:title>Abstract</jats:title><jats:p>Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl group, and as a result, molecules bearing multiple sulfones are versatile building blocks. This Review highlights the unique ability of 1,1‐ and 1,2‐bis(sulfones) to masquerade as a vast array of reactive synthons including methane polyanions, vinyl cations, and all‐carbon dipoles that would be difficult or impossible to access directly.</jats:p>
Umfang: 11193-11213
ISSN: 0947-6539
1521-3765
DOI: 10.1002/chem.201902019