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Buchumschlag von Synthesis of a [3Fe2S] Cluster with Low Redox Potential from [2Fe2S] Hydrogenase Models: Electrochemical and Photochemical Generation of Hydrogen
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Synthesis of a [3Fe2S] Cluster with Low Redox Potential from [2Fe2S] Hydrogenase Models: Electrochemical and Photochemical Generation of Hydrogen

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Zeitschriftentitel: European Journal of Inorganic Chemistry
Personen und Körperschaften: Gao, Weiming, Sun, Junliang, Li, Mingrun, Åkermark, Torbjörn, Romare, Kristina, Sun, Licheng, Åkermark, Björn
In: European Journal of Inorganic Chemistry, 2011, 2011, 7, S. 1100-1105
Medientyp: E-Article
Sprache: Englisch
veröffentlicht:
Wiley
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Zusammenfassung: <jats:title>Abstract</jats:title><jats:p>In the attempted replacement of carbon monoxide by thebis(phosphane) dppv in a dinuclear [2Fe2S] complex, a trinuclear [3Fe2S] complex with two bis(phosphane) ligands was unexpectedly obtained. On protonation, this gave a bridged hydride complex with an unusually low potential for the reduction of protons to molecular hydrogen. The redox potential also appears sufficiently positive for direct electron transfer from an excited [Ru(bpy)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup> sensitizer.</jats:p>
Umfang: 1100-1105
ISSN: 1434-1948
1099-0682
DOI: 10.1002/ejic.201000872