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Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)

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Zeitschriftentitel: Polymer Engineering & Science
Personen und Körperschaften: Li, Yan, Zhang, Gang, Wang, Xiaojun, Li, Zhi‐Min, Yang, Jie
In: Polymer Engineering & Science, 56, 2016, 1, S. 44-50
Medientyp: E-Article
Sprache: Englisch
veröffentlicht:
Wiley
Schlagwörter:
author_facet Li, Yan
Zhang, Gang
Wang, Xiaojun
Li, Zhi‐Min
Yang, Jie
Li, Yan
Zhang, Gang
Wang, Xiaojun
Li, Zhi‐Min
Yang, Jie
author Li, Yan
Zhang, Gang
Wang, Xiaojun
Li, Zhi‐Min
Yang, Jie
spellingShingle Li, Yan
Zhang, Gang
Wang, Xiaojun
Li, Zhi‐Min
Yang, Jie
Polymer Engineering & Science
Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
Materials Chemistry
Polymers and Plastics
General Chemistry
Materials Chemistry
Polymers and Plastics
General Chemistry
author_sort li, yan
spelling Li, Yan Zhang, Gang Wang, Xiaojun Li, Zhi‐Min Yang, Jie 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.24190 <jats:p>Poly(ether ether sulfone) (PEES) containing semi‐aromatic polyamides with methylene units and ether linkage were synthesized through the copolymerization of m‐dihydroxybenzene, 4,4‐dichlorodiphenylsulfone (DCDPS) and 1,6‐<jats:italic>N</jats:italic>, <jats:italic>N</jats:italic>′‐bis(4‐fluorobenzamide) hexane (BFBH) by the method of nucleophilic polymerization. The inherent viscosities of the resultant different proportion of copolymers were in the range of 0.39–0.78 dL/g. These copolymers were found to have excellent thermal properties with glass transition temperatures (<jats:italic>T</jats:italic><jats:sub>g</jats:sub>) of 121–177°C, and initial degradation temperatures (<jats:italic>T</jats:italic><jats:sub>d</jats:sub>) of 417.5–432.5°C. These copolymers showed good mechanical properties with tensile strengths of 45–83 MPa, storage modulus of 1.8–2.6 GPa. The complex viscosities of pure Poly(ether ether sulfone) (PEES) was in the range of 176,000–309.8 Pas from 0.01 to 100 Hz, the complex viscosities of the copolymers decreased significantly with the increase of semi‐aromatic amide content, the copolymers of 20% decreased from 4371 to 142.4 Pas (from 0.01 to 100 Hz), and the copolymers of 70% dropped from 634.6 Pas to 55.97 Pas (from 0.01 Hz to 100 Hz). All copolymers exhibited non‐Newtonian and shear‐thinning behavior. These results suggested the resultant copolymers possess better melt flowability that is beneficial for the materials’ melt processing. POLYM. ENG. SCI., 56:44–50, 2016. © 2015 Society of Plastics Engineers</jats:p> Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA) Polymer Engineering & Science
doi_str_mv 10.1002/pen.24190
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series Polymer Engineering & Science
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title Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_unstemmed Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_full Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_fullStr Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_full_unstemmed Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_short Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_sort synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (pees/pa)
topic Materials Chemistry
Polymers and Plastics
General Chemistry
Materials Chemistry
Polymers and Plastics
General Chemistry
url http://dx.doi.org/10.1002/pen.24190
publishDate 2016
physical 44-50
description <jats:p>Poly(ether ether sulfone) (PEES) containing semi‐aromatic polyamides with methylene units and ether linkage were synthesized through the copolymerization of m‐dihydroxybenzene, 4,4‐dichlorodiphenylsulfone (DCDPS) and 1,6‐<jats:italic>N</jats:italic>, <jats:italic>N</jats:italic>′‐bis(4‐fluorobenzamide) hexane (BFBH) by the method of nucleophilic polymerization. The inherent viscosities of the resultant different proportion of copolymers were in the range of 0.39–0.78 dL/g. These copolymers were found to have excellent thermal properties with glass transition temperatures (<jats:italic>T</jats:italic><jats:sub>g</jats:sub>) of 121–177°C, and initial degradation temperatures (<jats:italic>T</jats:italic><jats:sub>d</jats:sub>) of 417.5–432.5°C. These copolymers showed good mechanical properties with tensile strengths of 45–83 MPa, storage modulus of 1.8–2.6 GPa. The complex viscosities of pure Poly(ether ether sulfone) (PEES) was in the range of 176,000–309.8 Pas from 0.01 to 100 Hz, the complex viscosities of the copolymers decreased significantly with the increase of semi‐aromatic amide content, the copolymers of 20% decreased from 4371 to 142.4 Pas (from 0.01 to 100 Hz), and the copolymers of 70% dropped from 634.6 Pas to 55.97 Pas (from 0.01 Hz to 100 Hz). All copolymers exhibited non‐Newtonian and shear‐thinning behavior. These results suggested the resultant copolymers possess better melt flowability that is beneficial for the materials’ melt processing. POLYM. ENG. SCI., 56:44–50, 2016. © 2015 Society of Plastics Engineers</jats:p>
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author Li, Yan, Zhang, Gang, Wang, Xiaojun, Li, Zhi‐Min, Yang, Jie
author_facet Li, Yan, Zhang, Gang, Wang, Xiaojun, Li, Zhi‐Min, Yang, Jie, Li, Yan, Zhang, Gang, Wang, Xiaojun, Li, Zhi‐Min, Yang, Jie
author_sort li, yan
container_issue 1
container_start_page 44
container_title Polymer Engineering & Science
container_volume 56
description <jats:p>Poly(ether ether sulfone) (PEES) containing semi‐aromatic polyamides with methylene units and ether linkage were synthesized through the copolymerization of m‐dihydroxybenzene, 4,4‐dichlorodiphenylsulfone (DCDPS) and 1,6‐<jats:italic>N</jats:italic>, <jats:italic>N</jats:italic>′‐bis(4‐fluorobenzamide) hexane (BFBH) by the method of nucleophilic polymerization. The inherent viscosities of the resultant different proportion of copolymers were in the range of 0.39–0.78 dL/g. These copolymers were found to have excellent thermal properties with glass transition temperatures (<jats:italic>T</jats:italic><jats:sub>g</jats:sub>) of 121–177°C, and initial degradation temperatures (<jats:italic>T</jats:italic><jats:sub>d</jats:sub>) of 417.5–432.5°C. These copolymers showed good mechanical properties with tensile strengths of 45–83 MPa, storage modulus of 1.8–2.6 GPa. The complex viscosities of pure Poly(ether ether sulfone) (PEES) was in the range of 176,000–309.8 Pas from 0.01 to 100 Hz, the complex viscosities of the copolymers decreased significantly with the increase of semi‐aromatic amide content, the copolymers of 20% decreased from 4371 to 142.4 Pas (from 0.01 to 100 Hz), and the copolymers of 70% dropped from 634.6 Pas to 55.97 Pas (from 0.01 Hz to 100 Hz). All copolymers exhibited non‐Newtonian and shear‐thinning behavior. These results suggested the resultant copolymers possess better melt flowability that is beneficial for the materials’ melt processing. POLYM. ENG. SCI., 56:44–50, 2016. © 2015 Society of Plastics Engineers</jats:p>
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spelling Li, Yan Zhang, Gang Wang, Xiaojun Li, Zhi‐Min Yang, Jie 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.24190 <jats:p>Poly(ether ether sulfone) (PEES) containing semi‐aromatic polyamides with methylene units and ether linkage were synthesized through the copolymerization of m‐dihydroxybenzene, 4,4‐dichlorodiphenylsulfone (DCDPS) and 1,6‐<jats:italic>N</jats:italic>, <jats:italic>N</jats:italic>′‐bis(4‐fluorobenzamide) hexane (BFBH) by the method of nucleophilic polymerization. The inherent viscosities of the resultant different proportion of copolymers were in the range of 0.39–0.78 dL/g. These copolymers were found to have excellent thermal properties with glass transition temperatures (<jats:italic>T</jats:italic><jats:sub>g</jats:sub>) of 121–177°C, and initial degradation temperatures (<jats:italic>T</jats:italic><jats:sub>d</jats:sub>) of 417.5–432.5°C. These copolymers showed good mechanical properties with tensile strengths of 45–83 MPa, storage modulus of 1.8–2.6 GPa. The complex viscosities of pure Poly(ether ether sulfone) (PEES) was in the range of 176,000–309.8 Pas from 0.01 to 100 Hz, the complex viscosities of the copolymers decreased significantly with the increase of semi‐aromatic amide content, the copolymers of 20% decreased from 4371 to 142.4 Pas (from 0.01 to 100 Hz), and the copolymers of 70% dropped from 634.6 Pas to 55.97 Pas (from 0.01 Hz to 100 Hz). All copolymers exhibited non‐Newtonian and shear‐thinning behavior. These results suggested the resultant copolymers possess better melt flowability that is beneficial for the materials’ melt processing. POLYM. ENG. SCI., 56:44–50, 2016. © 2015 Society of Plastics Engineers</jats:p> Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA) Polymer Engineering & Science
spellingShingle Li, Yan, Zhang, Gang, Wang, Xiaojun, Li, Zhi‐Min, Yang, Jie, Polymer Engineering & Science, Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA), Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry
title Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_full Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_fullStr Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_full_unstemmed Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_short Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
title_sort synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (pees/pa)
title_unstemmed Synthesis and properties of copolymers of poly(ether ether sulfone)/semiaromatic polyamides (PEES/PA)
topic Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry
url http://dx.doi.org/10.1002/pen.24190